Influence of the Nature of the Nitrogen-Containing Base on the Kinetic Stability of Tetra(1,2,5-thiadiazolo)porphyrazine in Dimethyl Sulfoxide
- Authors: Petrov O.A.1, Kiselev A.N.1, Syrbu S.A.1
- 
							Affiliations: 
							- Ivanovo State University of Chemistry and Technology
 
- Issue: Vol 88, No 9 (2018)
- Pages: 2028-2033
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222460
- DOI: https://doi.org/10.1134/S1070363218090463
- ID: 222460
Cite item
Abstract
The state of tetrakis(1,2,5-thiadizole)porphyrazine in the DMSO medium was studied. The protontransfer complex that formed was found to be quite stable. This complex was shown to decompose in some strong base solutions after some delay. The influence of either the nature of nitrogen-containing base and NH acidity of the porphyrazine macrocycle on the destruction kinetics of proton-transfer tetrakis(1,2,5-thiadizole)-porphyrazine complexes was investigated.
About the authors
O. A. Petrov
Ivanovo State University of Chemistry and Technology
							Author for correspondence.
							Email: poa@isuct.ru
				                					                																			                												                	Russian Federation, 							Sheremetevskii pr. 7, Ivanovo, 153000						
A. N. Kiselev
Ivanovo State University of Chemistry and Technology
														Email: poa@isuct.ru
				                					                																			                												                	Russian Federation, 							Sheremetevskii pr. 7, Ivanovo, 153000						
S. A. Syrbu
Ivanovo State University of Chemistry and Technology
														Email: poa@isuct.ru
				                					                																			                												                	Russian Federation, 							Sheremetevskii pr. 7, Ivanovo, 153000						
Supplementary files
 
				
			 
					 
						 
						 
						 
						 
				 
  
  
  
  
  Email this article
			Email this article  Open Access
		                                Open Access Access granted
						Access granted Subscription Access
		                                		                                        Subscription Access
		                                					