Influence of the Nature of the Nitrogen-Containing Base on the Kinetic Stability of Tetra(1,2,5-thiadiazolo)porphyrazine in Dimethyl Sulfoxide
- Авторы: Petrov O.A.1, Kiselev A.N.1, Syrbu S.A.1
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Учреждения:
- Ivanovo State University of Chemistry and Technology
- Выпуск: Том 88, № 9 (2018)
- Страницы: 2028-2033
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222460
- DOI: https://doi.org/10.1134/S1070363218090463
- ID: 222460
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Аннотация
The state of tetrakis(1,2,5-thiadizole)porphyrazine in the DMSO medium was studied. The protontransfer complex that formed was found to be quite stable. This complex was shown to decompose in some strong base solutions after some delay. The influence of either the nature of nitrogen-containing base and NH acidity of the porphyrazine macrocycle on the destruction kinetics of proton-transfer tetrakis(1,2,5-thiadizole)-porphyrazine complexes was investigated.
Об авторах
O. Petrov
Ivanovo State University of Chemistry and Technology
Автор, ответственный за переписку.
Email: poa@isuct.ru
Россия, Sheremetevskii pr. 7, Ivanovo, 153000
A. Kiselev
Ivanovo State University of Chemistry and Technology
Email: poa@isuct.ru
Россия, Sheremetevskii pr. 7, Ivanovo, 153000
S. Syrbu
Ivanovo State University of Chemistry and Technology
Email: poa@isuct.ru
Россия, Sheremetevskii pr. 7, Ivanovo, 153000
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