Trimethylchlorosilane-Catalyzed Intramolecular Cyclization of 2-(2-Benzylideneaminoethyloxy)-1-phenylbenzo[ e ]-1,3,2-azaoxaphosphorin-4-one

M. N. Dimukhametov; G. A. Ivkova; Kh. R. Khayarov; R. Z. Musin; V. F. Mironov

doi:10.1134/S1070363218090311

Trimethylchlorosilane-Catalyzed Intramolecular Cyclization of 2-(2-Benzylideneaminoethyloxy)-1-phenylbenzo[e]-1,3,2-azaoxaphosphorin-4-one

Authors: Dimukhametov M.N.¹, Ivkova G.A.¹^,2, Khayarov K.R.², Musin R.Z.¹, Mironov V.F.¹^,2
Affiliations:
1. Arbuzov Institute of Organic and Physical Chemistry
2. Kazan (Volga Region) Federal University
Issue: Vol 88, No 9 (2018)
Pages: 1938-1940
Section: Letters to the Editor
URL: https://journals.rcsi.science/1070-3632/article/view/222437
DOI: https://doi.org/10.1134/S1070363218090311
ID: 222437

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Statistics

Abstract

A catalytic effect of trimethylchlorosilane on the intramolecular cyclization of 2-(2-benzylideneaminoethyloxy)-1-phenylbenzo[e]-1,3,2-azaoxaphosphorin-4-one into 3,4-benzo-5,10-diphenyl-1,5-diaza-7-oxabicyclo[4.3.1^1.6]decane-2,6-dione, formed as two diastereomers in a 1: 1 ratio, was studied.

Keywords

oxazaphosphorin, benzylideneaminoethanol, cage aminophosphonate, trimethylchlorosilane

About the authors

M. N. Dimukhametov

Arbuzov Institute of Organic and Physical Chemistry

Email: mironov@iopc.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

G. A. Ivkova

Arbuzov Institute of Organic and Physical Chemistry; Kazan (Volga Region) Federal University

Email: mironov@iopc.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088; Kazan, Tatarstan

Kh. R. Khayarov

Kazan (Volga Region) Federal University

Email: mironov@iopc.ru
Russian Federation, Kazan, Tatarstan

R. Z. Musin