Structure and Ion-Selective Properties of 2-Phosphorylphenols


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Abstract

The structure and ion-selective properties of some 2-phosphorylphenols were studied. It was shown that, irrespective of the nature of the substituents on the benzene ring and on the phosphorus atom, these compounds exhibit potentiometric selectivity to cesium cation. The crystal structures of 2-(diphenylphosphoryl)-4-ethylphenol and 2-[(diphenylphosphoryl)methyl]phenol were established.

About the authors

I. S. Ivanova

Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry

Email: mager1988@gmail.com
Russian Federation, Moscow; Leninskii pr. 31, Moscow, 119991

V. E. Baulin

Frumkin Institute of Physical Chemistry and Electrochemistry; Institute of Physiologically Active Substances

Author for correspondence.
Email: mager1988@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 119991; Chernogolovka, Moscow oblast, 142432

E. N. Pyatova

Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry

Email: mager1988@gmail.com
Russian Federation, Moscow; Leninskii pr. 31, Moscow, 119991

A. B. Ilyukhin

Kurnakov Institute of General and Inorganic Chemistry

Email: mager1988@gmail.com
Russian Federation, Moscow

E. N. Galkina

Kurnakov Institute of General and Inorganic Chemistry

Email: mager1988@gmail.com
Russian Federation, Moscow

I. A. Yakushev

Kurnakov Institute of General and Inorganic Chemistry

Email: mager1988@gmail.com
Russian Federation, Moscow

P. V. Dorovatovskii

Kurchatov Institute

Email: mager1988@gmail.com
Russian Federation, Moscow

A. Yu. Tsivadze

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: mager1988@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 119991


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