Email this article Modification of Phosphoryl Substituents of Phthalocyanines As a Route to Targeted Tuning of Lipophilic-Hydrophilic Properties
- Authors: Kalashnikova I.P.1, Baulin D.V.2, Baulin V.E.1,2, Tsivadze A.Y.2
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Affiliations:
- Institute of Physiologically Active Compounds
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 88, No 9 (2018)
- Pages: 1853-1859
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222414
- DOI: https://doi.org/10.1134/S1070363218090153
- ID: 222414
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Abstract
О′,О′-Diethyl-[2-(3,4-dicyanophenoxy)phenyl]phosphonate has been synthesized for the first time and introduced in template condensation on lithium and zinc cations to prepare a series of new neutral and acidic phthalocyanines containing four fragments of 2-oxyphenylphosphonic acid. A scheme of modification of the peripheral substituents at the phosphoryl group was developed allowing a targeted synthesis of phthalocyanine ligands and complexes soluble in organic solvents or aqueous media.
About the authors
I. P. Kalashnikova
Institute of Physiologically Active Compounds
Author for correspondence.
Email: ikalashn@ipac.ac.ru
Russian Federation, Severnyi proezd 1, Chernogolovka, 142432
D. V. Baulin
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: ikalashn@ipac.ac.ru
Russian Federation, Moscow
V. E. Baulin
Institute of Physiologically Active Compounds; Frumkin Institute of Physical Chemistry and Electrochemistry
Email: ikalashn@ipac.ac.ru
Russian Federation, Severnyi proezd 1, Chernogolovka, 142432; Moscow
A. Yu. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: ikalashn@ipac.ac.ru
Russian Federation, Moscow
