Electrophilic Catalysis in the Synthesis of Aryl Methyl- and Phenylphosphonochloridates
- Authors: Goryunov E.I.1, Goryunova I.B.1, Molchanova G.N.1, Kudryavtsev I.Y.1, Baulina T.V.1, Khodak A.A.1, Strelkova T.V.1, Brel V.K.1
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Affiliations:
- Nesmeyanov Institute of Organoelement Compounds
- Issue: Vol 88, No 9 (2018)
- Pages: 1776-1779
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222397
- DOI: https://doi.org/10.1134/S1070363218090025
- ID: 222397
Cite item
Abstract
The reaction of methyl- and phenylphosphonic dichlorides with phenols in the presence of anhydrous magnesium chloride as catalyst or magnesium metal as precatalyst provides a simple, efficient, and practical method of synthesis of the corresponding aryl methyl- and phenylphosphonochloridates.
About the authors
E. I. Goryunov
Nesmeyanov Institute of Organoelement Compounds
Author for correspondence.
Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
I. B. Goryunova
Nesmeyanov Institute of Organoelement Compounds
Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
G. N. Molchanova
Nesmeyanov Institute of Organoelement Compounds
Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
I. Yu. Kudryavtsev
Nesmeyanov Institute of Organoelement Compounds
Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
T. V. Baulina
Nesmeyanov Institute of Organoelement Compounds
Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
A. A. Khodak
Nesmeyanov Institute of Organoelement Compounds
Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
T. V. Strelkova
Nesmeyanov Institute of Organoelement Compounds
Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
V. K. Brel
Nesmeyanov Institute of Organoelement Compounds
Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991