Reaction of Benzylidene Chlorides with  О -Methyl Diethylphosphinothioate

M. B. Gazizov; G. D. Valieva; S. Yu. Ivanova; R. F. Karimova; R. K. Ismagilov; R. A. Khairullin

doi:10.1134/S1070363218080327

Reaction of Benzylidene Chlorides with О-Methyl Diethylphosphinothioate

Authors: Gazizov M.B.¹, Valieva G.D.¹, Ivanova S.Y.¹, Karimova R.F.¹, Ismagilov R.K.¹, Khairullin R.A.¹
Affiliations:
1. Kazan National Research Technological University, ul. K. Marksa 68
Issue: Vol 88, No 8 (2018)
Pages: 1754-1756
Section: Letters to the Editor
URL: https://journals.rcsi.science/1070-3632/article/view/222392
DOI: https://doi.org/10.1134/S1070363218080327
ID: 222392

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Abstract

О-Methyl diethylphosphinothioate reacts with benzylidene chlorides to form arenecarbthioaldehyde trimers and diethylphosphinoyl chloride. This result suggests that the reaction involves initial attack of the thione sulfur atom of the phosphinothioyl group on the methine carbon atom of the gem-dichloride.