Structure of the Condensation Products of D-Lactose and D-Maltose with SH-Contaning Carboxylic Acid Hydrazides
- Authors: Ershov A.Y.1, Vasileva M.Y.1, Lagoda I.V.2, Yakimansky A.V.1,3
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Affiliations:
- Institute of Macromolecular Compounds
- Research and Trial Medical and Biological Protection Center, State Research and Trial Institute of Military Medicine
- St. Petersburg State University
- Issue: Vol 88, No 6 (2018)
- Pages: 1199-1204
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222257
- DOI: https://doi.org/10.1134/S1070363218060245
- ID: 222257
Cite item
Abstract
The structure of the condensation products of D-lactose and D-maltose with sulfanylacetic, 3-sulfanylpropanoic, and 2-sulfanylbenzoic acid hydrazides has been studied 1H and 13C NMR spectroscopy. The condensation products obtained from the disaccharides and sulfanylacetohydrazide and 3-sulfanylpropanehydrazide have pyranose structure in the crystalline state, whereas those derived from 2-sulfanylbenzohydrazide have cyclic 1,3,4-benzothiadiazepine structure in crystal. All condensation products in solutions in most solvents (D2O, DMF-d7, DMSO-d6) exist as equilibrium mixtures of linear and cyclic pyranose and 1,3,4-benzothiadiazepine tautomers.
About the authors
A. Yu. Ershov
Institute of Macromolecular Compounds
Author for correspondence.
Email: ershov305@mail.ru
Russian Federation, Bol’shoi pr. V.O. 31, St. Petersburg, 199004
M. Yu. Vasileva
Institute of Macromolecular Compounds
Email: ershov305@mail.ru
Russian Federation, Bol’shoi pr. V.O. 31, St. Petersburg, 199004
I. V. Lagoda
Research and Trial Medical and Biological Protection Center, State Research and Trial Institute of Military Medicine
Email: ershov305@mail.ru
Russian Federation, St. Petersburg
A. V. Yakimansky
Institute of Macromolecular Compounds; St. Petersburg State University
Email: ershov305@mail.ru
Russian Federation, Bol’shoi pr. V.O. 31, St. Petersburg, 199004; Universitetskii pr. 26, St. Petersburg, 198504