Development of Chemical Polarization of Nuclei During Photolysis of Benzoquinones with Aromatic Amines
- Authors: Porkhun V.I.1, Gonik I.L.1, Zhukov S.S.1
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Affiliations:
- Volgograd State Technical University
- Issue: Vol 88, No 6 (2018)
- Pages: 1081-1085
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222231
- DOI: https://doi.org/10.1134/S1070363218060051
- ID: 222231
Cite item
Abstract
Formation of nuclei polarization via triplet mechanism has been observed and described, allowing reliable identification of ion-radicals stages of the reaction, estimation of the triplets and ion-radical pairs lifetime from the effects of chemical polarization of the nuclei. The data on relative values of isotropic and anisotropic interactions of unpaired electrons and nuclei have been obtained.
About the authors
V. I. Porkhun
Volgograd State Technical University
Author for correspondence.
Email: zs1978@mail.ru
Russian Federation, pr. Lenina 28, Volgograd, 400066
I. L. Gonik
Volgograd State Technical University
Email: zs1978@mail.ru
Russian Federation, pr. Lenina 28, Volgograd, 400066
S. S. Zhukov
Volgograd State Technical University
Email: zs1978@mail.ru
Russian Federation, pr. Lenina 28, Volgograd, 400066
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