Electroluminescent Iridium-Containing Functionalized Polynorbornenes Emitting Red Light


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Abstract

A new iridium(III) cyclometalated complex NBEpzIr(Tiq)2 {NBEpzH is 4-[(bicyclo[2.2.1]hept-5- en-2-yl)hydroxymethylidene]-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazole-3-on and TiqH is 1-(thien-2-yl)isoquinoline} was synthesized. Copolymers with carbazole and iridium-containing fragments in side chains were obtained on the basis of the synthesized monomer by the method of ring-opening metathesis polymerization. The copolymers exhibit intense photoluminescence and electroluminescence of deep red color.

About the authors

E. O. Platonova

G.A. Razuvaev Institute of Organometallic Chemistry

Email: lnb@iomc.ras.ru
Russian Federation, ul. Tropinina 49, Nizhny Novgorod, 603950

V. A. Ilichev

G.A. Razuvaev Institute of Organometallic Chemistry

Email: lnb@iomc.ras.ru
Russian Federation, ul. Tropinina 49, Nizhny Novgorod, 603950

L. N. Bochkarev

G.A. Razuvaev Institute of Organometallic Chemistry

Author for correspondence.
Email: lnb@iomc.ras.ru
Russian Federation, ul. Tropinina 49, Nizhny Novgorod, 603950


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