Synthesis and Complex Formation of Rhodamine-Substituted Spirobenzopyranindolines
- Authors: Solov’eva E.V.1, Rostovtseva I.A.1, Shepelenko K.E.1, Voloshin N.A.1, Chernyshev A.V.1, Borodkin G.S.1, Trofimova N.S.1, Metelitsa A.V.1, Minkin V.I.1
-
Affiliations:
- Research Institute of Physical and Organic Chemistry
- Issue: Vol 88, No 5 (2018)
- Pages: 968-972
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222194
- DOI: https://doi.org/10.1134/S1070363218050225
- ID: 222194
Cite item
Abstract
Novel spirobenzopyranindolines containing a rhodamine fragment linked to a benzopyran fragment with an aminomethylene spacer were synthesized by the reaction of 7-hydroxy-6-formyl-substituted spiropyrans and rhodamine B hydrazide. The synthesized spiropyrans in toluene and acetone are present in the spiropyran‒spirolactam form. The 5-methyl-substituted was the only to exhibit photochromism. Adding Zn(II), Ni(II), Co(II), and Cd(II) perchlorates to the spiropyran solutions leads to intense coloration due to complex formation.
Keywords
About the authors
E. V. Solov’eva
Research Institute of Physical and Organic Chemistry
Author for correspondence.
Email: evsoloveva@sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
I. A. Rostovtseva
Research Institute of Physical and Organic Chemistry
Email: evsoloveva@sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
K. E. Shepelenko
Research Institute of Physical and Organic Chemistry
Email: evsoloveva@sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
N. A. Voloshin
Research Institute of Physical and Organic Chemistry
Email: evsoloveva@sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
A. V. Chernyshev
Research Institute of Physical and Organic Chemistry
Email: evsoloveva@sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
G. S. Borodkin
Research Institute of Physical and Organic Chemistry
Email: evsoloveva@sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
N. S. Trofimova
Research Institute of Physical and Organic Chemistry
Email: evsoloveva@sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
A. V. Metelitsa
Research Institute of Physical and Organic Chemistry
Email: evsoloveva@sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
V. I. Minkin
Research Institute of Physical and Organic Chemistry
Email: evsoloveva@sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
![](/img/style/loading.gif)