Thermodynamics of Complex Formation of Ce3+ and La3+ Ions with Glycylglycine in Aqueous Solution


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Abstract

Enthalpy of the complex formation between diglycine (HL±) and Ce3+ or La3+ at 308.15 K and ionic strength of 0.5 mol/L (KNO3) has been determined by means of calorimetry. Thermodynamic parameters of the diglycine complexes formation with Ce3+ and La3+ at different metal to ligand molar ratios have been determined.

About the authors

A. I. Lytkin

Ivanovo State University of Chemistry and Technology

Author for correspondence.
Email: kdvkonkpd@yandex.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000

V. V. Chernikov

Ivanovo State University of Chemistry and Technology

Email: kdvkonkpd@yandex.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000

O. N. Krutova

Ivanovo State University of Chemistry and Technology

Email: kdvkonkpd@yandex.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000

D. K. Smirnova

Ivanovo State University of Chemistry and Technology

Email: kdvkonkpd@yandex.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000


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