Email this article Redox Isomerism of α-Ferrocenylcarbenium Ions
- Authors: Fomin V.M.1, Kochetkova K.S.1, Klyuchevskii K.V.1
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Affiliations:
- N.I. Lobachevskii State University of Nizhny Novgorod
- Issue: Vol 88, No 5 (2018)
- Pages: 948-953
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222188
- DOI: https://doi.org/10.1134/S1070363218050183
- ID: 222188
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Abstract
The formation of α-ferrocenylcarbenium ions FcC+H2 (λmax 600 nm) and FcC+HCH3 (λmax 730 nm) and their redox isomerism at the protonation of ferrocenylmethanol and vinylferrocene was proved using the method of electronic spectroscopy. The effect on the process of the solvent and acid nature as well as of hydrogen peroxide additives is discussed.
About the authors
V. M. Fomin
N.I. Lobachevskii State University of Nizhny Novgorod
Author for correspondence.
Email: niih325@bk.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
K. S. Kochetkova
N.I. Lobachevskii State University of Nizhny Novgorod
Email: niih325@bk.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
K. V. Klyuchevskii
N.I. Lobachevskii State University of Nizhny Novgorod
Email: niih325@bk.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
