Preparation of a Polymer via Condensation of o-Phenylenediamine with p-Xylylene Dibromide and Its Properties


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Abstract

Condensation of para-dibromoxylene and ortho-phenylenediamine in glass ampule at 150°С in an alkaline aqueous solution has yielded polymer with completely substituted N–H hydrogen atoms, capable of formation of polymeric cation-radicals. Complexes of this polymer and N,N,N',N'-tetrabenzyl-o-phenylenediamine with Co(II), Ni(II), Cu(II), and Ag(I) have been obtained, and their structure has been studied.

About the authors

S. Z. Ismailova

Nagiev Institute of Catalysis and Inorganic Chemistry

Author for correspondence.
Email: sabina.chemstry.1986@mail.ru
Azerbaijan, pr. G. Dzhavida 113, Baku, AZ, 1143

A. A. Medjidov

Nagiev Institute of Catalysis and Inorganic Chemistry

Email: sabina.chemstry.1986@mail.ru
Azerbaijan, pr. G. Dzhavida 113, Baku, AZ, 1143

P. A. Fatullaeva

Nagiev Institute of Catalysis and Inorganic Chemistry

Email: sabina.chemstry.1986@mail.ru
Azerbaijan, pr. G. Dzhavida 113, Baku, AZ, 1143

R. J. Gasymov

Institute of Radiation Problems

Email: sabina.chemstry.1986@mail.ru
Azerbaijan, Baku


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