Nucleophilic Substitution in 4-Bromo-5-nitrophthalodinitrile: XVI.1 4-(1H-Benzotriazol-1-yl)-5-[(4-carboxyphenyl)oxy/sulfanyl]- phthalonitriles and Cobalt Phthalocyanines Thereof
- Authors: Znoiko S.A.1, Kuz’min I.A.1, Tikhomirova T.V.1, Smirnov N.N.1, Maizlish V.E.1, Vashurin A.S.1,2, Shaposhnikov G.P.1
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Affiliations:
- Research Institute of Macroheterocyclic Chemistry, Ivanovo State
- Kazan Federal University, ul. Kremlevskaya 18
- Issue: Vol 88, No 4 (2018)
- Pages: 751-757
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222142
- DOI: https://doi.org/10.1134/S1070363218040205
- ID: 222142
Cite item
Abstract
A method of synthesis of 4-(1H-benzotriazol-1-yl)-5-[(4-carboxyphenyl)oxy]- and -5-[(4-carboxyphenyl) sulfanyl]phthalonitriles starting with 4-bromo-5-nitrophthalonitriles was developed. The synthesized phthalonitriles were used to prepare cobalt tetra-4-(1H-benzotriazol-1-yl)-tetra-5-[(4-carboxyphenyl)oxy/sulfanyl]phthalocyanines. The spectral and catalytic properties of the resulting octasubstituted phthalocyanines were studied.
About the authors
S. A. Znoiko
Research Institute of Macroheterocyclic Chemistry, Ivanovo State
Author for correspondence.
Email: znoykosa@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300
I. A. Kuz’min
Research Institute of Macroheterocyclic Chemistry, Ivanovo State
Email: znoykosa@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300
T. V. Tikhomirova
Research Institute of Macroheterocyclic Chemistry, Ivanovo State
Email: znoykosa@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300
N. N. Smirnov
Research Institute of Macroheterocyclic Chemistry, Ivanovo State
Email: znoykosa@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300
V. E. Maizlish
Research Institute of Macroheterocyclic Chemistry, Ivanovo State
Email: znoykosa@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300
A. S. Vashurin
Research Institute of Macroheterocyclic Chemistry, Ivanovo State; Kazan Federal University, ul. Kremlevskaya 18
Email: znoykosa@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300; Kazan, Tatarstan, 420008
G. P. Shaposhnikov
Research Institute of Macroheterocyclic Chemistry, Ivanovo State
Email: znoykosa@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300