Synthesis and Properties of Tetra-4-{[(1,1'-biphenyl)-4-yl]oxy}phthalocyanines and Their Sulfonic Acid Derivatives


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Abstract

The template condensation of 4-{[(1,1'-biphenyl)-4-yl]oxy}phthalonitrile with cobalt, copper, and magnesium acetate resulted in the synthesis of metal phthalocyanines. Sulfochlorination of the latter followed by hydrolysis gave the corresponding sulfonic acid derivatives. The spectral characteristics and chemical properties of the synthesized compounds were studied.

About the authors

T. V. Tikhomirova

Research Institute of Macroheterocyclic Chemistry

Author for correspondence.
Email: tararjkina@mail.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300

A. A. Peledina

Research Institute of Macroheterocyclic Chemistry

Email: tararjkina@mail.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300

V. E. Maizlish

Research Institute of Macroheterocyclic Chemistry

Email: tararjkina@mail.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300

A. S. Vashurin

Research Institute of Macroheterocyclic Chemistry; Kazan Federal University

Email: tararjkina@mail.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300; Kazan, Tatarstan

G. P. Shaposhnikov

Research Institute of Macroheterocyclic Chemistry

Email: tararjkina@mail.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300


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