Six-Nuclear Complexes of Platinum(II) and Palladium(II) with Mercamine and β-Mercaptoethanol
- Authors: Azizova A.N.1, Tagiev D.B.1, Kasumov S.G.2, Gasanov K.I.2
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Affiliations:
- Academician M. Nagiev Institute of Catalysis and Inorganic Chemistry
- Azerbaijan Medical University
- Issue: Vol 88, No 3 (2018)
- Pages: 505-508
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222065
- DOI: https://doi.org/10.1134/S1070363218030179
- ID: 222065
Cite item
Abstract
The platinum(II) and palladium(II) complexes [Pt6(SCH2CH2NH2)8]Cl4 and [Pd6(SCH2CH2OH)8 Cl4· 5H2O with mercamine and β-mercaptoethanol, respectively, were synthesized. It was found on the basis of the comparison of IR and X-ray electron spectra of the ligands and complexes, and also of the data of X-ray diffraction analysis that the bidentate coordination of ligands through sulfur and nitrogen atoms is realized in the platinum(II) complex. In the palladium(II) complex β-mercaptoethanol is coordinated in a mixed-mode type. In both complexes sulfur atoms of the ligands occupy a bridging position.
About the authors
A. N. Azizova
Academician M. Nagiev Institute of Catalysis and Inorganic Chemistry
Author for correspondence.
Email: iradam@rambler.ru
Azerbaijan, pr. G. Dzhavida 113, Baku, AZ1143
D. B. Tagiev
Academician M. Nagiev Institute of Catalysis and Inorganic Chemistry
Email: iradam@rambler.ru
Azerbaijan, pr. G. Dzhavida 113, Baku, AZ1143
Sh. G. Kasumov
Azerbaijan Medical University
Email: iradam@rambler.ru
Azerbaijan, Baku
Kh. I. Gasanov
Azerbaijan Medical University
Email: iradam@rambler.ru
Azerbaijan, Baku