Spectral Luminescent Properties of 2-Aryl-5-(2,6-dimethoxyphenyl)-1H-1,3,4-oxadiazoles


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Abstract

2-Aryl-5-(2,6-dimethoxyphenyl)-1H-1,3,4-oxadiazoles were synthesized by cyclization reaction of benzoylbenzohydrazides in SOCl2, and their spectral luminescent properties were studied. The oxadiazoles containing phenyl or o-methoxyphenyl substituents in the position 2 were shown to luminesce with a high quantum yield in polar and nonpolar solvents. The replacement of these substituents by 2-hydroxyphenyl group led to oxadiazole intensely emitting only in highly polar aprotic DMSO.

About the authors

I. E. Mikhailov

Research Institute of Physical and Organic Chemistry; Southern Scientific Center, Federal Research Center

Author for correspondence.
Email: mikhail@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090; Rostov-on-Don

Yu. M. Artyushkina

Research Institute of Physical and Organic Chemistry

Email: mikhail@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090

G. A. Dushenko

Research Institute of Physical and Organic Chemistry

Email: mikhail@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090

O. I. Mikhailova

Research Institute of Physical and Organic Chemistry

Email: mikhail@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090

Yu. V. Revinskii

Southern Scientific Center, Federal Research Center

Email: mikhail@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don

V. I. Minkin

Research Institute of Physical and Organic Chemistry

Email: mikhail@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090


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