Synthesis and Some Transformations of Cyclic Acetals of Propargyl Aldehyde

S. A. Lukicheva; A. A. Golovanov; Ya. A. Nachkebia; V. V. Bekin; G. Z. Raskildina; S. S. Zlotskii

doi:10.1134/S1070363218020226

Synthesis and Some Transformations of Cyclic Acetals of Propargyl Aldehyde

Authors: Lukicheva S.A.¹, Golovanov A.A.¹, Nachkebia Y.A.¹, Bekin V.V.¹, Raskildina G.Z.², Zlotskii S.S.²
Affiliations:
1. Togliatti State University
2. Ufa State Oil Technical University
Issue: Vol 88, No 2 (2018)
Pages: 330-333
Section: Letters to the Editor
URL: https://journals.rcsi.science/1070-3632/article/view/222019
DOI: https://doi.org/10.1134/S1070363218020226
ID: 222019

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Abstract

Dehydrobromination of 2-(1,2-dibromoethyl)-1,3-dioxocyclanes with sodium amide in liquid ammonia provided cyclic acetals of propargyl aldehyde. Reactions of the resulting compounds with nitrile oxides and diazomethane afforded the corresponding isoxazole and pyrazole derivatives.