Enviar artigo por via de e-mail Synthesis of New Unsaturated Amines by The Stevens Rearrangement
- Autores: Manukyan M.1, Gyulnazaryan A.1, Babakhanyan A.2, Shahkhatuni A.3, Barseghyan K.1
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Afiliações:
- Institute of Organic Chemistry of Scientific-Technological Center of Organic and Pharmaceutical Chemistry
- Armenian State Pedagogical University after Kh. Abovyan
- Scientific-Technological Center of Organic and Pharmaceutical Chemistry
- Edição: Volume 88, Nº 2 (2018)
- Páginas: 325-329
- Seção: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/222018
- DOI: https://doi.org/10.1134/S1070363218020214
- ID: 222018
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Resumo
Monoalkylation of 1,4-dichlorobut-2-ene with prop-2-yn-1-ol under phase-transfer catalysis conditions led to the formation of 1-(prop-2-yn-1-yloxy)-4-chlorobut-2-ene. The latter reacted with dimethylamine to afford N,N-dimethyl-4-(prop-2-yn-1-yloxy)but-2-enyl-1-amine. Its quaternization afforded new ammonium salts containing 4-(prop-2-yn-1-yloxy)but-2-enyl group. Unsaturated tertiary amines formed as a result of Stevens 3,2-rearrangement of quaternary salts.
Sobre autores
M. Manukyan
Institute of Organic Chemistry of Scientific-Technological Center of Organic and Pharmaceutical Chemistry
Autor responsável pela correspondência
Email: manukyanmeri@gmail.com
Armênia, pr. Azatutyan 26, Yerevan, 0014
A. Gyulnazaryan
Institute of Organic Chemistry of Scientific-Technological Center of Organic and Pharmaceutical Chemistry
Email: manukyanmeri@gmail.com
Armênia, pr. Azatutyan 26, Yerevan, 0014
A. Babakhanyan
Armenian State Pedagogical University after Kh. Abovyan
Email: manukyanmeri@gmail.com
Armênia, Yerevan
A. Shahkhatuni
Scientific-Technological Center of Organic and Pharmaceutical Chemistry
Email: manukyanmeri@gmail.com
Armênia, Yerevan
K. Barseghyan
Institute of Organic Chemistry of Scientific-Technological Center of Organic and Pharmaceutical Chemistry
Email: manukyanmeri@gmail.com
Armênia, pr. Azatutyan 26, Yerevan, 0014
