Azomethines Based on Pyridoxal-Derived Aromatic Aldehydes


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Abstract

The reaction of pyridoxal with 2,4-dihydroxybenzaldehyde in a hydrochloric acid solution gave 1-(5-formyl-2,4-dihydroxyphenyl)-7-hydroxy-6-methyl-1,3-dihydrofuro[3,4-c]pyridin-5-ium chloride. Treatment of the latter with sodium hydride in ethanol afforded a free aldehyde in 85% yield. A series of azomethines and imidazolidines was obtained by reacting the obtained aldehyde with various amines and diamines.

About the authors

L. K. Kibardina

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Author for correspondence.
Email: kibardina@iopc.ru
Russian Federation, ul. Arbuzova 8, Kazan, Tatarstan, 420088

A. V. Trifonov

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center; Kazan National Research Technological University

Email: kibardina@iopc.ru
Russian Federation, ul. Arbuzova 8, Kazan, Tatarstan, 420088; Kazan, Tatarstan

Yu. I. Ivanova

Kazan National Research Technological University

Email: kibardina@iopc.ru
Russian Federation, Kazan, Tatarstan

M. A. Pudovik

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Email: kibardina@iopc.ru
Russian Federation, ul. Arbuzova 8, Kazan, Tatarstan, 420088

E. M. Pudovik

Kazan (Volga Region) Federal University

Email: kibardina@iopc.ru
Russian Federation, Kazan, Tatarstan

A. R. Burilov

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center; Kazan National Research Technological University

Email: kibardina@iopc.ru
Russian Federation, ul. Arbuzova 8, Kazan, Tatarstan, 420088; Kazan, Tatarstan


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