Email this article Plasticization of Cellulose Nitrate by 4-Nitrophtalic Acid Esters
- Authors: Golubev A.E.1, Neshitova A.N.2, Singin P.V.3, Kuvshinova S.A.2, Burmistrov V.A.2, Koifman O.I.2,4
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Affiliations:
- Research Institute of Polymer Materials
- Ivanovo State University of Chemistry and Technology
- Ivanovo Research Institute of Film Materials and Synthetic Leather for Technical Uses
- Krestov Institute of Solution Chemistry
- Issue: Vol 87, No 12 (2017)
- Pages: 3086-3092
- Section: Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
- URL: https://journals.rcsi.science/1070-3632/article/view/221870
- DOI: https://doi.org/10.1134/S107036321712057X
- ID: 221870
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Abstract
The rheological properties of nitrocellulose solutions in cyclohexanone in the presence of phthalic and 4-nitrophthalic diester plasticizers were studied by rotational viscometry to reveal a behavior similar to that of Newtonian fluids. The activation parameters of the viscous flow regime were calculated. An influence of nitroplasticizers and dibutyl phthalate on the rheology of nitrocellulose was established. The influence of plasticizers on the mechanical properties of nitrocellulose films was discussed.
About the authors
A. E. Golubev
Research Institute of Polymer Materials
Author for correspondence.
Email: niipm@perm.ru
Russian Federation, ul. Chistopol’skaya 16, Perm
A. N. Neshitova
Ivanovo State University of Chemistry and Technology
Email: niipm@perm.ru
Russian Federation, Ivanovo
P. V. Singin
Ivanovo Research Institute of Film Materials and Synthetic Leather for Technical Uses
Email: niipm@perm.ru
Russian Federation, Ivanovo
S. A. Kuvshinova
Ivanovo State University of Chemistry and Technology
Email: niipm@perm.ru
Russian Federation, Ivanovo
V. A. Burmistrov
Ivanovo State University of Chemistry and Technology
Email: niipm@perm.ru
Russian Federation, Ivanovo
O. I. Koifman
Ivanovo State University of Chemistry and Technology; Krestov Institute of Solution Chemistry
Email: niipm@perm.ru
Russian Federation, Ivanovo; Ivanovo
