Specific Features of Scandium Chloride Extraction with a Mixture of Tributyl Phosphate and Molecular Iodine


Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

Features of interphase distribution of scandium chloride in the systems containing tributyl phosphate and molecular iodine have been analyzed. Significant electrolytic dissociation of the formed complex scandium chloride with tributyl phosphate and iodine in the organic phase (almost complete at tributyl phosphate concentration 80–100%) has been observed. The increase in electroconductivity of the solutions of scandium chloride has been most prominent at the ratio of scandium chloride and iodine corresponding to the formation of monosolvate. Accounting for electrolytic dissociation in the organic phase allowed the description of the interphase extraction of scandium chloride in the studied systems.

About the authors

V. I. Kuzmin

Institute of Chemistry and Chemical Engineering, Siberian Branch

Author for correspondence.
Email: kuzmin_vi@mail.ru
Russian Federation, Akademgorodok 50/24, Krasnoyarsk, 660036

A. A. Kuzmina

Siberian Federal University

Email: kuzmin_vi@mail.ru
Russian Federation, Krasnoyarsk


Copyright (c) 2017 Pleiades Publishing, Ltd.

This website uses cookies

You consent to our cookies if you continue to use our website.

About Cookies