Synthesis of precursors to new tripodal phosphine oxide ligands
- Authors: Kudryavtsev I.Y.1, Bykhovskaya O.V.1, Aladzheva I.M.1, Baulina T.V.1, Brel’ V.K.1
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Affiliations:
- Nesmeyanov Institute of Organoelement Compounds
- Issue: Vol 87, No 11 (2017)
- Pages: 2744-2747
- Section: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/221659
- DOI: https://doi.org/10.1134/S1070363217110366
- ID: 221659
Cite item
Abstract
A number of precursors of new tripodal ligands was obtained by hydroxyethylation of the starting tris(2-hydroxyphenyl)phosphine oxide, followed by conversion of the resulting tris[2-(2-hydroxyethoxy) phenyl]phosphine oxide to trimesylate. The treatment of the latter with LiBr or NaN3 afforded the corresponding tribromo and triazido derivatives.
About the authors
I. Yu. Kudryavtsev
Nesmeyanov Institute of Organoelement Compounds
Author for correspondence.
Email: zaq@ineos.ac.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
O. V. Bykhovskaya
Nesmeyanov Institute of Organoelement Compounds
Email: zaq@ineos.ac.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
I. M. Aladzheva
Nesmeyanov Institute of Organoelement Compounds
Email: zaq@ineos.ac.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
T. V. Baulina
Nesmeyanov Institute of Organoelement Compounds
Email: zaq@ineos.ac.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
V. K. Brel’
Nesmeyanov Institute of Organoelement Compounds
Email: zaq@ineos.ac.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991