Email this article Synthesis and structure of trimethylantimony dimethacrylate
- Authors: Gushchin A.V.1, Lakhanina E.A.1, Andreev P.V.1
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Affiliations:
- Lobachevskii National Research State University of Nizhny Novgorod
- Issue: Vol 87, No 11 (2017)
- Pages: 2596-2599
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221576
- DOI: https://doi.org/10.1134/S1070363217110135
- ID: 221576
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Abstract
The reaction of trimethylantimony with methacrylic acid in the presence of tert-butyl hydroperoxide gave trimethylantimony dimethacrylate Me3Sb(O2CCMe=CH2)2 whose structure was confirmed by elemental analysis and IR, 1H and 13C NMR, and mass spectra. According to the X-ray diffraction data, the title compound is a trigonal–bipyramidal antimony complex with three methyl group in the pyramid base and two methacrylate ligands in the apices.
About the authors
A. V. Gushchin
Lobachevskii National Research State University of Nizhny Novgorod
Author for correspondence.
Email: gushchin4@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
E. A. Lakhanina
Lobachevskii National Research State University of Nizhny Novgorod
Email: gushchin4@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
P. V. Andreev
Lobachevskii National Research State University of Nizhny Novgorod
Email: gushchin4@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
