Colloid and nanosized catalysts in organic synthesis: XVII. Reductive amination of carbonitriles in the presence of supported nickel nanoparticles

Yu. V. Popov; V. M. Mokhov; S. E. Latyshova; A. O. Panov; P. M. Shirkhanyan

doi:10.1134/S1070363217110068

Colloid and nanosized catalysts in organic synthesis: XVII. Reductive amination of carbonitriles in the presence of supported nickel nanoparticles

Authors: Popov Y.V.¹, Mokhov V.M.¹, Latyshova S.E.¹, Panov A.O.¹, Shirkhanyan P.M.¹
Affiliations:
1. Volgograd State Technical University
Issue: Vol 87, No 11 (2017)
Pages: 2546-2551
Section: Article
URL: https://journals.rcsi.science/1070-3632/article/view/221556
DOI: https://doi.org/10.1134/S1070363217110068
ID: 221556

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Abstract

Reductive amination of carbonitriles catalyzed by nickel nanoparticles applied onto a solid support in a plug flow reactor in the gas phase or the gas–liquid–solid catalyst system occurs at atmospheric pressure of hydrogen affording the nonsymmetrical secondary or tertiary amines. The effect of the support type on the target product yield and conversion of the substrate has been studied.