Email this article Synthesis of isomerically pure δ-chloro-γ-vinylketones
- Authors: Shakhmaev R.N.1, Sunagatullina A.S.1, Alieva R.M.1, Zorin V.V.1
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Affiliations:
- Ufa State Petroleum Technological University
- Issue: Vol 87, No 10 (2017)
- Pages: 2472-2476
- Section: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/221519
- DOI: https://doi.org/10.1134/S1070363217100310
- ID: 221519
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Abstract
An efficient method for the synthesis of isomerically pure δ-chloro-γ-vinylketones was developed on the basis of monoalkylation of β-ketoesters with the individual isomers of 1,3-dichloropropene and the subsequent decarbalkoxylation of the resulting chlorovinyl derivatives under optimized Krapcho decarboxylation conditions.
About the authors
R. N. Shakhmaev
Ufa State Petroleum Technological University
Author for correspondence.
Email: biochem@rusoil.net
Russian Federation, ul. Kosmonavtov 1, Ufa, 450062
A. Sh. Sunagatullina
Ufa State Petroleum Technological University
Email: biochem@rusoil.net
Russian Federation, ul. Kosmonavtov 1, Ufa, 450062
R. M. Alieva
Ufa State Petroleum Technological University
Email: biochem@rusoil.net
Russian Federation, ul. Kosmonavtov 1, Ufa, 450062
V. V. Zorin
Ufa State Petroleum Technological University
Email: biochem@rusoil.net
Russian Federation, ul. Kosmonavtov 1, Ufa, 450062
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