Physicochemical properties of compounds of alkyl sulfates and cationic copper(II) complexes with some organic reagents
- Authors: Makarova N.M.1, Kulapina E.G.1, Skaptsov А.А.1
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Affiliations:
- Chernyshevskii Saratov National Research State University
- Issue: Vol 87, No 10 (2017)
- Pages: 2320-2326
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221411
- DOI: https://doi.org/10.1134/S1070363217100127
- ID: 221411
Cite item
Abstract
Compounds of alkyl sulfates and cationic copper(II) complexes with some organic reagents (pyridine, 1,10-phenanthroline, 2,2'-dipyridyl) were prepared, and their physicochemical characteristics (composition, thermal stability, solubility) were determined. The synthesized compounds are poorly soluble (solubility product KS = n×10–20–n×10–22) and thermally stable (90–260°С). An effect of the hydrophobilicity of alkyl sulfates on the UV characteristics of the copper(II)–organic reagent systems and on the solubility of the studied compounds was evaluated.
About the authors
N. M. Makarova
Chernyshevskii Saratov National Research State University
Author for correspondence.
Email: makarova2114@mail.ru
Russian Federation, ul. Astrakhanskaya 83, Saratov, 410012
E. G. Kulapina
Chernyshevskii Saratov National Research State University
Email: makarova2114@mail.ru
Russian Federation, ul. Astrakhanskaya 83, Saratov, 410012
А. А. Skaptsov
Chernyshevskii Saratov National Research State University
Email: makarova2114@mail.ru
Russian Federation, ul. Astrakhanskaya 83, Saratov, 410012