Colloid and nanosized catalysts in organic synthesis: XVI. 1  Continuous hydrogenation of carbonitriles catalyzed by nickel nanoparticles applied on a support

Yu. V. Popov; V. M. Mokhov; S. E. Latyshova; D. N. Nebykov; A. O. Panov; M. Yu. Pletneva

doi:10.1134/S107036321710005X

Colloid and nanosized catalysts in organic synthesis: XVI.¹ Continuous hydrogenation of carbonitriles catalyzed by nickel nanoparticles applied on a support

Authors: Popov Y.V.¹, Mokhov V.M.¹, Latyshova S.E.¹, Nebykov D.N.¹, Panov A.O.¹, Pletneva M.Y.¹
Affiliations:
1. Volgograd State Technical University
Issue: Vol 87, No 10 (2017)
Pages: 2276-2281
Section: Article
URL: https://journals.rcsi.science/1070-3632/article/view/221394
DOI: https://doi.org/10.1134/S107036321710005X
ID: 221394

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Abstract

Conversion of the starting nitriles and selectivity of the products formation during continuous hydrogenation of various nitriles catalyzed by Ni⁰/Ceokar-2 have been studied as functions of temperature. Performing the process at temperature 120–260°С has led to the formation of a mixture of products containing di- and trialkylamines as well as the corresponding imines and enamines.