Email this article Effect of the alkylidene spacer and the p-tert-butylthiacalix[4]arene macrocyclic platform on the reactivity of the hydroxyl groups in the acylation reaction
- Authors: Padnya P.L.1, Bayarashov Е.Е.1, Potrekeeva О.S.1, Stoikov I.I.1
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Affiliations:
- Butlerov Institute of Chemistry
- Issue: Vol 87, No 9 (2017)
- Pages: 2111-2114
- Section: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/221305
- DOI: https://doi.org/10.1134/S107036321709033X
- ID: 221305
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Abstract
A series of cone and 1,3-alternate p-tert-butylthiacalix[4]arenes tetrasubstituted at the lower rim simultaneously by the amide, ester, and carboxyl functions were synthesized. The reactivity of the synthesized compounds depends on the length of the alkylidene spacer. The N-(hydroxyethyl)amide derivatives do not react with succinic anhydride, whereas the N-(3-hydroxypropyl)amide derivatives react to form acylation products.
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About the authors
P. L. Padnya
Butlerov Institute of Chemistry
Email: ivan.stoikov@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
Е. Е. Bayarashov
Butlerov Institute of Chemistry
Email: ivan.stoikov@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
О. S. Potrekeeva
Butlerov Institute of Chemistry
Email: ivan.stoikov@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
I. I. Stoikov
Butlerov Institute of Chemistry
Author for correspondence.
Email: ivan.stoikov@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
