Synthesis of new diarylmethanes on the basis of resorcinol derivatives and amino acetals containing an aminoethylidenebisphosphonate fragment


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Abstract

New ethylenebisphosphorylated α-amino acetals were synthesized by the reaction of aminoacetaldehyde dimethyl acetal with ethenylidenebisphosphonates (Michael reaction). It was found that the synthesized compounds react with 2-methylresorcinol and resorcinol in the presence of HCl to form previously unknown diarylalkylammonium salts containing ethylidenebisphosphonate groups.

About the authors

L. I. Vagapova

Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center

Author for correspondence.
Email: vagapovan@mail.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

E. M. Makhrus

Kazan National Research Technological University

Email: vagapovan@mail.ru
Russian Federation, Kazan, Tatarstan

A. R. Burilov

Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center

Email: vagapovan@mail.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

M. A. Pudovik

Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center

Email: vagapovan@mail.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088


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