Email this article Synthesis of new p-tert-butylcalix[4]arene derivatives containing photopolymerizable 1,3-butadiyne fragments
- Authors: Burilov V.A.1, Valiyakhmetova A.M.1, Aukhadieva R.I.1, Solovieva S.E.1,2, Antipin I.S.1,2
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Affiliations:
- Kazan (Volga region) Federal University
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
- Issue: Vol 87, No 9 (2017)
- Pages: 1946-1951
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221205
- DOI: https://doi.org/10.1134/S1070363217090092
- ID: 221205
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Abstract
Successive functionalization of p-tert-butylcalix[4]arene afforded a bifunctional derivative containing photopolymerizable pentacosa-10,12-diynoic acid fragments on the upper rim and propargyl groups on the lower rim of the macrocycle having a cone structure. The functionalization can be readily accomplished via copper-catalyzed azide–alkyne cycloaddition under mild conditions.
About the authors
V. A. Burilov
Kazan (Volga region) Federal University
Author for correspondence.
Email: ultrav@bk.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
A. M. Valiyakhmetova
Kazan (Volga region) Federal University
Email: ultrav@bk.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
R. I. Aukhadieva
Kazan (Volga region) Federal University
Email: ultrav@bk.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
S. E. Solovieva
Kazan (Volga region) Federal University; Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: ultrav@bk.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008; ul. Arbuzova 8, Kazan, Tatarstan, 420008
I. S. Antipin
Kazan (Volga region) Federal University; Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: ultrav@bk.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008; ul. Arbuzova 8, Kazan, Tatarstan, 420008
