Reactions of dialkyl (3,5-di-tert-butyl-4-oxocyclohex-2,5-dienylidenemethyl)phosphonates with alcohols and some transformations of the adducts
- Authors: Starodubtseva R.R.1, Gibadullina E.M.1, Pazilova N.B.2, Syakaev V.V.1, Pudovik M.A.1, Burilov A.R.1
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Affiliations:
- Arbuzov Institute of Organic and Physical Chemistry
- Kazan National Research Technological University
- Issue: Vol 87, No 9 (2017)
- Pages: 1908-1912
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221192
- DOI: https://doi.org/10.1134/S1070363217090031
- ID: 221192
Cite item
Abstract
Reactions of dialkyl [(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)methyl]phosphonates with butyl, benzyl and propargyl alcohols in the presence of catalytic amounts of trifluoromethanesulfonic acid resulted in the formation of nucleophilic 1,6-addition products. Azide-alkyne cycloaddition reaction of dimethyl (3,5-di-tert-butyl-4-hydroxyphenyl)(prop-2-ynyloxy)methylphosphonate with benzyl azide and 1,3-bis-(2-azidoethoxy)benzene in the presence of copper sulfate and sodium ascorbate afforded 1,2,3-triazoles with sterically hindered phenol fragments.
About the authors
R. R. Starodubtseva
Arbuzov Institute of Organic and Physical Chemistry
Author for correspondence.
Email: azmramilya@gmail.com
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
E. M. Gibadullina
Arbuzov Institute of Organic and Physical Chemistry
Email: azmramilya@gmail.com
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
N. B. Pazilova
Kazan National Research Technological University
Email: azmramilya@gmail.com
Russian Federation, Kazan, Tatarstan
V. V. Syakaev
Arbuzov Institute of Organic and Physical Chemistry
Email: azmramilya@gmail.com
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
M. A. Pudovik
Arbuzov Institute of Organic and Physical Chemistry
Email: azmramilya@gmail.com
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
A. R. Burilov
Arbuzov Institute of Organic and Physical Chemistry
Email: azmramilya@gmail.com
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
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