Email this article Betti base in the synthesis of chiral bisphosphorylated thioureas
- Authors: Metlushka K.E.1,2, Sadkova D.N.1, Nikitina K.A.1, Lodochnikova O.A.1, Kataeva O.N.1,2, Alfonsov V.A.1,2
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Affiliations:
- A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
- Butlerov Institute of Chemistry
- Issue: Vol 87, No 9 (2017)
- Pages: 1893-1902
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221189
- DOI: https://doi.org/10.1134/S1070363217090018
- ID: 221189
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Abstract
Phosphorylation of a naphthol hydroxy group of thiophosphorylated thiourea obtained by reaction of diethyl thiophosphoryl isothiocyanate with 1-(α-aminobenzyl)-2-naphthol (Betti base) afforded a number of chiral bisphosphorylated thioureas. Molecular structure of the obtained compounds was studied by single crystal X-ray diffraction. The capacity of the studied compounds for dimerization due to the intermolecular N–H···S hydrogen bonding was revealed.
About the authors
K. E. Metlushka
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center; Butlerov Institute of Chemistry
Email: alfonsov@yandex.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088; ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
D. N. Sadkova
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: alfonsov@yandex.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
K. A. Nikitina
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: alfonsov@yandex.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
O. A. Lodochnikova
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: alfonsov@yandex.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
O. N. Kataeva
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center; Butlerov Institute of Chemistry
Email: alfonsov@yandex.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088; ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
V. A. Alfonsov
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center; Butlerov Institute of Chemistry
Author for correspondence.
Email: alfonsov@yandex.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088; ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
