Email this article β-Bromo-substituted palladium(II) tetraphenylporphyrins. Synthesis and spectral properties
- Authors: Chizhova N.V.1, Mal’tseva O.V.1, Mamardashvili N.Z.1, Koifman O.I.1,2,3
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Affiliations:
- Krestov Institute of Solution Chemistry
- Ivanovo State University of Chemistry and Technology
- Research Institute of Macroheterocyclic Chemistry
- Issue: Vol 87, No 7 (2017)
- Pages: 1580-1583
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220787
- DOI: https://doi.org/10.1134/S1070363217070222
- ID: 220787
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Abstract
Bromination of (5,10,15,20-tetraphenylporphyrinato)palladium(II) and [5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinato]palladium(II) with N-bromosuccinimide in chloroform–dimethylformamide and chloroform afforded mono-, tetra-, and octabromo derivatives substituted at the pyrrole rings. The products were identified by electronic absorption, 1H NMR, and mass spectra and elemental analyses.
About the authors
N. V. Chizhova
Krestov Institute of Solution Chemistry
Author for correspondence.
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045
O. V. Mal’tseva
Krestov Institute of Solution Chemistry
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045
N. Zh. Mamardashvili
Krestov Institute of Solution Chemistry
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045
O. I. Koifman
Krestov Institute of Solution Chemistry; Ivanovo State University of Chemistry and Technology; Research Institute of Macroheterocyclic Chemistry
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045; Sheremetevskii pr. 7, Ivanovo, 153000; Sheremetevskii pr. 7, Ivanovo, 153000
