Nucleophilic substitution in 4-bromo-5-nitrophthalodinitrile: XV. Synthesis of bis-4,5-(phenylsulfanyl)phthalonitrile, octakis-4,5-(phenylsulfanyl)phthalocyanines, and their sulfo and alkylsulfamoyl derivatives

S. A. Znoiko; E. S. Golovashova; O. V. Potekhina; D. B. Berezin; M. A. Serova; V. E. Maizlish; G. P. Shaposhnikov

doi:10.1134/S1070363217070209

Nucleophilic substitution in 4-bromo-5-nitrophthalodinitrile: XV. Synthesis of bis-4,5-(phenylsulfanyl)phthalonitrile, octakis-4,5-(phenylsulfanyl)phthalocyanines, and their sulfo and alkylsulfamoyl derivatives

Authors: Znoiko S.A.¹, Golovashova E.S.¹, Potekhina O.V.¹, Berezin D.B.¹, Serova M.A.¹, Maizlish V.E.¹, Shaposhnikov G.P.¹
Affiliations:
1. Research Institute of Macroheterocyclic Chemistry
Issue: Vol 87, No 7 (2017)
Pages: 1562-1571
Section: Article
URL: https://journals.rcsi.science/1070-3632/article/view/220764
DOI: https://doi.org/10.1134/S1070363217070209
ID: 220764

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Abstract

Novel water- and organic-soluble derivatives of octakis-4,5-(sulfanylphenyl)phthalocyanine and its magnesium and aluminum complexes were synthesized starting from 4,5-bis(phenylsulfanyl)phthalonitrile obtained by nucleophilic substitution of the bromine and nitro group in 4-bromo-5-nitrophthalonitrile. Spectral and luminescence characteristics of the newly synthesized compounds were studied.