Synthesis of new ferrocene derivatives with a 4,5-dichloroisothiazole fragment
- Authors: Kletskov A.V.1, Kolesnik I.A.1, Dikusar E.A.1, Zhukovskaya N.A.1, Potkin V.I.1
-
Affiliations:
- Institute of Physical Organic Chemistry
- Issue: Vol 87, No 6 (2017)
- Pages: 1167-1171
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220166
- DOI: https://doi.org/10.1134/S107036321706010X
- ID: 220166
Cite item
Abstract
Conjugates of ferrocene and 4,5-dichloroisothiazole were synthesized, where the ferrocene and isothiazole moieties are linked through various structural fragments. The acylation of ferrocene with 4,5- dichloroisothiazole-3-carbonyl chloride gave (4,5-dichloroisothiazol-3-yl) ferrocenyl ketone; the acylation of aminomethylferrocene furnished the corresponding amide. The esterification of ferrocene-1,1′-dicarboxylic acid with 4,5-dichloroisothiazol-3-yl-methanol resulted in the formation of the corresponding ester. The condensation of 1,1′-diacetylferrocene with 4,5-dichloroisothiazole-3-carbaldehyde afforded ferrocenophane containing 4,5-dichloroisothiazole moieties.
Keywords
About the authors
A. V. Kletskov
Institute of Physical Organic Chemistry
Author for correspondence.
Email: avkletskov@gmail.com
Belarus, ul. Surganova 13, Minsk, 220072
I. A. Kolesnik
Institute of Physical Organic Chemistry
Email: avkletskov@gmail.com
Belarus, ul. Surganova 13, Minsk, 220072
E. A. Dikusar
Institute of Physical Organic Chemistry
Email: avkletskov@gmail.com
Belarus, ul. Surganova 13, Minsk, 220072
N. A. Zhukovskaya
Institute of Physical Organic Chemistry
Email: avkletskov@gmail.com
Belarus, ul. Surganova 13, Minsk, 220072
V. I. Potkin
Institute of Physical Organic Chemistry
Email: avkletskov@gmail.com
Belarus, ul. Surganova 13, Minsk, 220072