Email this article Imines derived from 4-methyl-4-diphenylphosphorylpentan-2-one and potassium salts of aminocarboxylic acids
- Authors: Dimukhametov M.N.1, Mironov V.F.1,2, Tatarinov D.A.1,2
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Affiliations:
- Arbuzov Institute of Organic and Physical Chemistry
- Kazan (Volga Region) Federal University
- Issue: Vol 87, No 4 (2017)
- Pages: 882-884
- Section: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/219602
- DOI: https://doi.org/10.1134/S1070363217040363
- ID: 219602
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Abstract
An effective procedure for the preparation of imines based on 4-methyl-4-diphenylphosphorylpentan-2-one, aminoacetic, aminopropionic, and aminobutyric acids with yields of 90–95% was developed. Reaction of dimephosphone (4-methyl-4-dimethoxyphosphorilpentan-2-one) with potassium salts of these amino acids led to methylation of the carboxy group of the amino acid to form potassium salt of 2-methyl-4-oxopentylphosphonic acid methyl ester.
About the authors
M. N. Dimukhametov
Arbuzov Institute of Organic and Physical Chemistry
Email: mironov@iopc.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
V. F. Mironov
Arbuzov Institute of Organic and Physical Chemistry; Kazan (Volga Region) Federal University
Author for correspondence.
Email: mironov@iopc.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088; Kazan, Tatarstan
D. A. Tatarinov
Arbuzov Institute of Organic and Physical Chemistry; Kazan (Volga Region) Federal University
Email: mironov@iopc.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088; Kazan, Tatarstan
