Email this article Hydroethoxycarbonylation of α-olefins at low pressure of carbon(II) oxide in the presence of the PdCl2(PPh3)2–PPh3–AlCl3 system
- Authors: Suerbaev K.A.1, Kudaibergenov N.Z.1, Vavasori A.2
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Affiliations:
- Al-Farabi Kazakh National University
- Ca’Foscari University of Venice
- Issue: Vol 87, No 4 (2017)
- Pages: 707-712
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/219175
- DOI: https://doi.org/10.1134/S1070363217040089
- ID: 219175
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Abstract
High catalytic activity of the PdCl2(PPh3)2–PPh3–AlCl3 system containing AlCl3 as promotor has been demonstrated in the reaction of hydroethoxycarbonylation of hexene-1 and octene-1 at low pressure of carbon(II) oxide (≤25 atm). The reaction yields linear and branched products. The optimal conditions of the process have been elaborated. The target products yield is 84.6–93.8%.
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About the authors
Kh. A. Suerbaev
Al-Farabi Kazakh National University
Author for correspondence.
Email: khsuerbaev@mail.ru
Kazakhstan, ul. Tole Bi 96A, Almaty, 050012
N. Zh. Kudaibergenov
Al-Farabi Kazakh National University
Email: khsuerbaev@mail.ru
Kazakhstan, ul. Tole Bi 96A, Almaty, 050012
A. Vavasori
Ca’Foscari University of Venice
Email: khsuerbaev@mail.ru
Italy, Venice
