Solvation and coordination interactions of tetrapyridylporphyrin in aqueous solutions. Thermal stability


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Abstract

The results from application of calorimetric method for studying the energetics of the interparticle interaction in aqueous solutions of tetrapyridylporphyrin have been discussed. The influence of the nature of functional substitution, isomerism of the molecule on the enthalpies of dissolution and complexation with copper and zinc cations by tetrapyridylporphyrin derivatives has been elucidated. The thermal stability of crystalline samples of tetrapyridylporphyrin compounds under atmospheric oxygen conditions has been evaluated.

About the authors

N. M. Berezina

Ivanovo State University of Chemistry and Technology (ISUCT)

Author for correspondence.
Email: sky_berezina@rambler.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000

M. B. Berezin

Krestov Institute of Solution Chemistry, Russian Academy of Sciences

Email: sky_berezina@rambler.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040

Do Ngoc Minh

Ivanovo State University of Chemistry and Technology (ISUCT)

Email: sky_berezina@rambler.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000

M. I. Bazanov

Ivanovo State University of Chemistry and Technology (ISUCT)

Email: sky_berezina@rambler.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000


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