Phase transitions and thermodynamic properties of lanthanide compounds LnAO4 (A = P, V, Nb)
- Authors: Gavrichev K.S.1, Ryumin M.A.1, Nikiforova G.E.1, Bryukhanova K.I.1, Khoroshilov A.V.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- Issue: Vol 87, No 3 (2017)
- Pages: 583-590
- Section: Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
- URL: https://journals.rcsi.science/1070-3632/article/view/219040
- DOI: https://doi.org/10.1134/S1070363217030343
- ID: 219040
Cite item
Abstract
The influence of structural phase transitions, features of electronic structure, and magnetic transformation on the temperature dependence of the heat capacity of LnAO4 (A = P, V, Nb) compounds has been considered. It has been shown that the sum of the contributions to the thermodynamic functions due to the phase transition can vary depending on the lanthanide ion. The contribution to the standard entropy caused by low-temperature phase transitions is the most significant.
About the authors
K. S. Gavrichev
Kurnakov Institute of General and Inorganic Chemistry
Author for correspondence.
Email: gavrich@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
M. A. Ryumin
Kurnakov Institute of General and Inorganic Chemistry
Email: gavrich@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
G. E. Nikiforova
Kurnakov Institute of General and Inorganic Chemistry
Email: gavrich@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
K. I. Bryukhanova
Kurnakov Institute of General and Inorganic Chemistry
Email: gavrich@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
A. V. Khoroshilov
Kurnakov Institute of General and Inorganic Chemistry
Email: gavrich@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
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