Email this article Synthesis and structure of the palladium complexes [Ph3P(CH2)3PPh3][PdBr4], [Ph3P(CH2)3PPh3][Pd2Br6]·DMF, and [Ph3P(CH2)3PPh3][PdBr3(DMSO-S)]2
- Authors: Sharutin V.V.1, Sharutina O.K.1, Senchurin V.S.1, Il’chenko I.A.1, Andreev P.V.2
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Affiliations:
- National Research South Ural State University
- National Research Nizhny Novgorod State University
- Issue: Vol 87, No 1 (2017)
- Pages: 122-127
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/217979
- DOI: https://doi.org/10.1134/S1070363217010194
- ID: 217979
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Abstract
Complexes [Ph3P(CH2)3PPh3][PdBr4] and [Ph3P(CH2)3PPh3][Pd2Br6]·DMF were synthesized by the reaction of dihydrogentetrabromopalladic acid with trimethylenebis(triphenylphosphonium) dibromide in water with subsequent recrystallization from N,N-dimethylformamide. The recrystallization of the first of them from dimethyl sulfoxide leads to the formation of the complex [Ph3P(CH2)3PPh3][PdBr3(DMSO-S)]2. Structure of the complexes was investigated by the X-ray diffraction (XRD) analysis.
About the authors
V. V. Sharutin
National Research South Ural State University
Author for correspondence.
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
O. K. Sharutina
National Research South Ural State University
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
V. S. Senchurin
National Research South Ural State University
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
I. A. Il’chenko
National Research South Ural State University
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
P. V. Andreev
National Research Nizhny Novgorod State University
Email: vvsharutin@rambler.ru
Russian Federation, Nizhny Novgorod
