Email this article Nucleophilic addition of aromatic amide oximes to [2-B10H9NCC2H5]– anion
- Authors: Zhizhin K.Y.1, Kuznetsov N.T.1, Bolotin D.S.2, Demakova M.Y.2, Daines E.A.2, Avdontseva M.S.2, Zhdanov A.P.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- St. Petersburg State University
- Issue: Vol 87, No 1 (2017)
- Pages: 37-43
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/217831
- DOI: https://doi.org/10.1134/S107036321701008X
- ID: 217831
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Abstract
A series of closo-decaborate anions containing an O-iminoacylamide oxime fragment were synthesized by nucleophilic addition of aromatic amide oximes to 2-propionitrilium closo-decaborate anion. The isolated compounds were characterized by IR, 1H, 13C–{1H}, and 11B–{1H} NMR, and mass spectra. The structure of (Ph4P)[2-B10H9NH=C(Et)ON=C(NH2)C6H4Me-2] was determined by single-crystal X-ray analysis.
About the authors
K. Yu. Zhizhin
Kurnakov Institute of General and Inorganic Chemistry
Email: dmitriy.s.bolotin@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 119991
N. T. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry
Email: dmitriy.s.bolotin@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 119991
D. S. Bolotin
St. Petersburg State University
Author for correspondence.
Email: dmitriy.s.bolotin@gmail.com
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
M. Ya. Demakova
St. Petersburg State University
Email: dmitriy.s.bolotin@gmail.com
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
E. A. Daines
St. Petersburg State University
Email: dmitriy.s.bolotin@gmail.com
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
M. S. Avdontseva
St. Petersburg State University
Email: dmitriy.s.bolotin@gmail.com
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. P. Zhdanov
Kurnakov Institute of General and Inorganic Chemistry
Email: dmitriy.s.bolotin@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 119991
