Email this article Kinetics and mechanism of oxidative polymerization of phenylenediamines
- Authors: Strakhov I.S.1, Mezhuev Y.O.1, Korshak Y.V.1, Stilman M.I.1
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Affiliations:
- Mendeleev University of Chemical Technology of Russia
- Issue: Vol 86, No 12 (2016)
- Pages: 2682-2688
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/216751
- DOI: https://doi.org/10.1134/S1070363216120185
- ID: 216751
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Abstract
Kinetics of oxidative polymerization of three isomeric phenylenediamines in aqueous hydrochloric acid solutions initialed by ammonium persulfate has been studied, and kinetic parameters of non-catalytic and catalytic stages of polymerization have been determined. The observed effect of the isomeric substrates structure on the activation energy of the catalytic and non-catalytic stages has been explained.
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About the authors
I. S. Strakhov
Mendeleev University of Chemical Technology of Russia
Email: valsorja@mail.ru
Russian Federation, Miusskaya pl. 9, Moscow, 125047
Ya. O. Mezhuev
Mendeleev University of Chemical Technology of Russia
Author for correspondence.
Email: valsorja@mail.ru
Russian Federation, Miusskaya pl. 9, Moscow, 125047
Yu. V. Korshak
Mendeleev University of Chemical Technology of Russia
Email: valsorja@mail.ru
Russian Federation, Miusskaya pl. 9, Moscow, 125047
M. I. Stilman
Mendeleev University of Chemical Technology of Russia
Email: valsorja@mail.ru
Russian Federation, Miusskaya pl. 9, Moscow, 125047
