Tetracoordinate phosphorus cage compounds with endocyclic P–C bonds: Synthesis and reactivity
- Authors: Mironov V.F.1,2, Ivkova G.A.1, Burnaeva L.M.1
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Affiliations:
- Kazan (Volga Region) Federal University
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
- Issue: Vol 86, No 12 (2016)
- Pages: 2624-2635
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/216686
- DOI: https://doi.org/10.1134/S1070363216120094
- ID: 216686
Cite item
Abstract
The survey summarizes modern methods of synthesis and reactivity of tetracoordinated phosphorus cage compounds containing one or more endocyclic P–C bonds (phosphine oxides, phosphinates and phosphonates, phosphatripticenes and others). Intramolecular cyclization reactions including electrophilic aromatic substitution with unsaturated organophosphorus compounds, reactions of P–H-derivatives with carbonyl compounds as well as cycloaddition reactions involving I–IV-coordinated phosphorus derivatives are considered.
About the authors
V. F. Mironov
Kazan (Volga Region) Federal University; Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Author for correspondence.
Email: mironov@iopc.ru
Russian Federation, Kazan, Tatarstan; ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
G. A. Ivkova
Kazan (Volga Region) Federal University
Email: mironov@iopc.ru
Russian Federation, Kazan, Tatarstan
L. M. Burnaeva
Kazan (Volga Region) Federal University
Email: mironov@iopc.ru
Russian Federation, Kazan, Tatarstan