Email this article 3-(4-N,N-dimethylaminophenyl)-2-nitro-1-phenylprop-2-en-1-one by 13C NMR spectroscopy and X-ray diffraction analysis
- Authors: Berestovitskaya V.M.1, Baichurin R.I.1, Islamov D.R.2, Kataeva O.N.3, Aboskalova N.I.1, Trukhin E.V.1
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Affiliations:
- Herzen State Pedagogical University of Russia
- Kazan Federal University
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
- Issue: Vol 86, No 10 (2016)
- Pages: 2312-2317
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/216331
- DOI: https://doi.org/10.1134/S107036321610011X
- ID: 216331
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Abstract
X-ray diffraction analysis established that 3-(4-N,N-dimethylaminophenyl)-2-nitro-1-phenylprop-2-en-1-one has E configuration both in crystal and in solution. The benzoyl group deviates from the styrene plane by 89.83°. The elongation of the C=C bond and shortening of its surrounding single bonds points to a high polarization of the molecule, implying a great contribution of the bipolar structure to the ground state.
About the authors
V. M. Berestovitskaya
Herzen State Pedagogical University of Russia
Author for correspondence.
Email: kohrgpu@yandex.ru
Russian Federation, nab. reki Moiki 48, St. Petersburg, 191186
R. I. Baichurin
Herzen State Pedagogical University of Russia
Email: kohrgpu@yandex.ru
Russian Federation, nab. reki Moiki 48, St. Petersburg, 191186
D. R. Islamov
Kazan Federal University
Email: kohrgpu@yandex.ru
Russian Federation, Kazan, Tatarstan
O. N. Kataeva
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: kohrgpu@yandex.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
N. I. Aboskalova
Herzen State Pedagogical University of Russia
Email: kohrgpu@yandex.ru
Russian Federation, nab. reki Moiki 48, St. Petersburg, 191186
E. V. Trukhin
Herzen State Pedagogical University of Russia
Email: kohrgpu@yandex.ru
Russian Federation, nab. reki Moiki 48, St. Petersburg, 191186
