The effect of the nitrogen-containing base nature on the kinetic of zinc complex formation with octa( m -trifluoromethylphenyl)porphyrazine in benzene

O. A. Petrov; G. V. Osipova

doi:10.1134/S1070363216080223

The effect of the nitrogen-containing base nature on the kinetic of zinc complex formation with octa(m-trifluoromethylphenyl)porphyrazine in benzene

Authors: Petrov O.A.¹, Osipova G.V.¹
Affiliations:
1. Ivanovo State University of Chemistry and Technology
Issue: Vol 86, No 8 (2016)
Pages: 1912-1916
Section: Article
URL: https://journals.rcsi.science/1070-3632/article/view/215989
DOI: https://doi.org/10.1134/S1070363216080223
ID: 215989

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Abstract
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Abstract

The effect of morpholine and piperidine on the kinetics of complex formation between zinc acetate and octa(m-trifluoromethylphenyl)porphyrazine in benzene has been studied. Possible scheme of the complex formation has been suggested. The effect of proton-accepting properties of the additive on the rate constants has been demonstrated.

Keywords

octa(m-trifluoromethylphenyl)porphyrazine, zinc acetate, nitrogen-containing base, complex formation, kinetics

About the authors

O. A. Petrov

Ivanovo State University of Chemistry and Technology

Author for correspondence.
Email: poa@isuct.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000

G. V. Osipova