Synthesis and structure of tris(4-fluorophenyl)antimony dicarboxylates
- Authors: Sharutin V.V.1, Sharutina O.K.1
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Affiliations:
- South Ural State University
- Issue: Vol 86, No 8 (2016)
- Pages: 1902-1906
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215975
- DOI: https://doi.org/10.1134/S107036321608020X
- ID: 215975
Cite item
Abstract
The interaction of tris(4-fluorophenyl)antimony with chloroacetic, 4-nitrophenylacetic, and benzoic acids in diethyl ether in the presence of tert-butyl hydroperoxide has yielded tris(4-fluorophenyl)antimony dicarboxylates, their Sb atoms bearing distorted trigonal bipyramid coordination with the carboxylate ligands in the axial positions. The intramolecular contacts between Sb atom and carbonyl O atom are formed in the molecules of the products. Their crystal packing is determined by weak intermolecular hydrogen bonds of the H···F and H···O=C types.
About the authors
V. V. Sharutin
South Ural State University
Author for correspondence.
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
O. K. Sharutina
South Ural State University
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080