Email this article Phenylsulfanyl(fluoro)-substituted phthalocyanine nickel complexes: Synthesis and self-association
- Authors: Koptyaev A.I.1, Galanin N.E.1, Shaposhnikov G.P.1
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Affiliations:
- Ivanovo State University of Chemistry and Technology
- Issue: Vol 86, No 7 (2016)
- Pages: 1679-1683
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215735
- DOI: https://doi.org/10.1134/S1070363216070240
- ID: 215735
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Abstract
By cross-condensation of 4,5-bis(phenylsulfanyl)phthalonitrile (A) with tetrafluorophthalo-nitrile (B) in the presence of nickel acetate nickel phthalocyanines of the type A4, A3B, ABAB, AABB were synthesized. Their spectral properties were studied and the propensity to association in benzene solutions was revealed. The concentration of complexes where the association becomes notable decreases with the increased dipole moment of the phthalocyanine.
About the authors
A. I. Koptyaev
Ivanovo State University of Chemistry and Technology
Email: nik-galanin@yandex.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000
N. E. Galanin
Ivanovo State University of Chemistry and Technology
Author for correspondence.
Email: nik-galanin@yandex.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000
G. P. Shaposhnikov
Ivanovo State University of Chemistry and Technology
Email: nik-galanin@yandex.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000
