Solubility of d-elements salts in organic and aqueous-organic solvents: III. Influence of intermolecular association on solubility of cadmium bromide and iodide
- Authors: Bogachev N.A.1, Gorbunov A.O.1, Nikolskii A.B.1, Skripkin M.Y.1
-
Affiliations:
- St. Petersburg State University
- Issue: Vol 86, No 7 (2016)
- Pages: 1539-1544
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215623
- DOI: https://doi.org/10.1134/S107036321607001X
- ID: 215623
Cite item
Abstract
Solubility in the systems CdX2–H2O–Solv (X = Br, I; Solv = dimethyl sulfoxide, N,N-dimethyl acetamide, N,N-dimethyl formamide, and 1,4-dioxane) at 25°C was measured by the isothermal saturation method. A relation between the shape of the solubility isotherm and the structure of the binary solvent depending on its composition was found. Positions of solubility maxima and isotherms inflection points in the most cases correlate with destruction of intermolecular associates formed by solvent components.
About the authors
N. A. Bogachev
St. Petersburg State University
Author for correspondence.
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. O. Gorbunov
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. B. Nikolskii
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
M. Yu. Skripkin
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
![](/img/style/loading.gif)