Complex formation of magnesium and calcium ions with trimethylenediamine-N,N,N’,N’-tetraacetic acid


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Abstract

Stability constants and heat effects of the formation reactions of magnesium and calcium trimethylenediaminetetraacetates at 298.15 K and ionic strength of 0.1, 0.5, and 1.0 (mol/L KNO3) have been determined by means of potentiometry and calorimetry. Standard thermodynamic parameters (log K0, ΔrG0, ΔrH0, and ΔrS0) of the studied equilibriums have been determined.

About the authors

S. N. Gridchin

Ivanovo State University of Chemistry and Technology

Author for correspondence.
Email: sergei_gridchin@mail.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000


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